| # | Joueur | Club | Pens | P/match |
|---|---|---|---|---|
| 1 | K. Mbappe | Real Madrid | 8 | 0.21 |
| 2 | Mikel Oyarzabal | Real Sociedad | 7 | 0.18 |
| 3 | Ante Budimir | Osasuna | 6 | 0.16 |
| 4 | V. Muriqi | Mallorca | 5 | 0.13 |
| 5 | Vinicius Junior | Real Madrid | 4 | 0.11 |
| 6 | Borja Iglesias | Celta | 4 | 0.11 |
| 7 | Lamine Yamal | Barça | 3 | 0.08 |
| 8 | Raphinha | Barça | 3 | 0.08 |
| 9 | Lucas Boyé | Alaves | 3 | 0.08 |
| 10 | Akor Adams | Sevilla FC | 3 | 0.08 |
| 11 | T. Martinez | Alaves | 1 | 0.03 |
| 12 | R. Lewandowski | Barça | 1 | 0.03 |
| 13 | Cucho Hernández | Real Betis | 1 | 0.03 |
| 14 | G. Guruzeta | Athletic | 1 | 0.03 |
